Diaquabis[2-(2-pyridylmethoxy)pyrazine-κN 4]bis(thiocyanato-κN)cobalt(II)
نویسنده
چکیده
In the title complex, [Co(NCS)(2)(C(10)H(9)N(3)O)(2)(H(2)O)(2)], the Co(II) ion is located on a crystallographic twofold rotation axis and is in a slightly distorted octa-hedral CoN(4)O(2) coordination environment. The dihedral angle between the pyridine and pyrazine rings is 85.86 (10)°. In the crystal structure, inter-molecular O-H⋯N and O-H⋯S hydrogen bonds link complex mol-ecules into a three-dimensional network.
منابع مشابه
Aqua(hexamethylenetetramine-κN)bis(methanol-κO)bis(thiocyanato-κN)cobalt(II)
In the title complex, [Co(NCS)(2)(C(6)H(12)N(4))(CH(4)O)(2)(H(2)O)], the six-coordinated Co atom has a slightly distorted octa-hedral geometry. The molecules are linked by intermolecular O-H⋯S and O-H⋯N hydrogen bonds, forming a three- dimensional crystal structure. Intramolecular C-H⋯N and C-H⋯O hydrogen bonds are also present.
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عنوان ژورنال:
دوره 64 شماره
صفحات -
تاریخ انتشار 2008